It is done by vapourising metal compounds to the watch case, layer by layer, in a heated vacuum. The second and perhaps most commonly used method is Physical Vapour Deposition (PVD). It involves blasting carbon onto the watch case and then supercooling it, resulting in a strong bond to the stainless steel/titanium surface. The first method is a coating: DLC, short for “Diamond Like Carbon. Sidebar: There are broadly 2 options to treat metals to achieve a black appearance, apart from using outright carbon itself. The titanium case is lightweight and offers a nice heft while on the wrist.
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